HazCom: The Nine Pictograms and Your Duties

What each symbol means, what a compliant label and safety data sheet must carry, and how long the paperwork has to survive.
The pictograms
| Flame | Flammables. Solvent adhesives, propane. |
| Flame over circle | Oxidizers. Some curing accelerants and cleaning agents. |
| Exploding bomb | Explosives, self-reactives, organic peroxides. |
| Gas cylinder | Compressed or liquefied gas. Oxy-acetylene sets. |
| Corrosion | Skin and eye burns, or corrosive to metal. Masonry acid cleaners. |
| Skull and crossbones | Acute toxicity. Can be fatal. |
| Exclamation mark | Irritant, skin sensitizer, milder acute toxicity. Some caulks and bleaches. |
| Health hazard | Carcinogen, respiratory sensitizer, reproductive toxicity. Silica-bearing products, some epoxy hardeners. |
| Environment | Aquatic toxicity. NOT OSHA-enforced: environmental hazards are the EPA's remit. |
Labels
| A shipped label must carry | Product identifier, signal word, hazard statements, pictograms, precautionary statements, and supplier name, address and phone |
| Pictogram border | Red diamond on a shipped container |
| Workplace labels | May use an alternative system, so a black border or no pictogram can still be compliant in-house |
| The common failure | Decanting into an unlabeled container. That is the citation most sites actually get. |
Safety data sheets
| 16 sections, fixed order | Sections 1 to 11 and 16 are the ones OSHA enforces |
| Sections 12 to 15 | Ecological, disposal, transport, regulatory. Present on the sheet, but other agencies regulate them, so OSHA does not enforce them. |
| Accessible | Available to employees on every shift, without asking permission |
Training and records
| Training when | At initial assignment, and whenever a NEW HAZARD is introduced. A new product with a hazard already covered does not trigger it; a new hazard does. |
| Retention | SDSs count as employee exposure records under 29 CFR 1910.1020 and must be kept 30 YEARS, or a substitute record of chemical identity, where it was used and when |
| Construction | 29 CFR 1926.59 states its requirements are identical to 1910.1200. Your standard is not different. |
Sources: osha.gov
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